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Organometallic Chemistry, by Gary O. Spessard, Gary L. Miessler
PDF Download Organometallic Chemistry, by Gary O. Spessard, Gary L. Miessler
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Designed with the needs of both undergraduate and graduate students in mind, Organometallic Chemistry, Second Edition, covers the fundamentals of organometallic chemistry by presenting seminal experiments, analyzing real data, and offering the most comprehensive problem sets available. The text opens with careful and patient explanations of the structure and bonding of organometallic compounds, providing a uniquely accessible introduction to the subject for undergraduate students. Later chapters build on this foundation with in-depth coverage of organometallic reaction mechanisms, more advanced topics of catalysis, carbene complexes, metathesis, applications of organometallic chemistry to organic synthesis, and cluster compounds.
FEATURES
* Numerous in-chapter worked examples and expansive end-of-chapter problem sets. Covering a wide spectrum of difficulty, the end-of-chapter problems range from basic practice problems to more advanced analytical ones; many of these are directly referenced to the current chemical literature.
* An experimental approach--illustrated by both groundbreaking classic experiments and cutting-edge contemporary ones-- that not only teaches students what is now known about organometallic chemistry, but also how we know what we know
* Real-world applications--highlighted throughout the text-- that engage students and reveal the relevance of organometallic chemistry to the world of industry
NEW TO THE SECOND EDITION
* Updated and expanded coverage of the latest developments in the field, including IR, NMR, and mass spectroscopy; catalysis; carbene complexes; metathesis and polymerization; and applications to organic synthesis
* More extensive treatments of industrial applications, including hydroformylation, uses of Grubbs and Schrock metal carbene catalysts, SHOP, palladium-catalyzed cross-couplings, and more
* 50% more in-chapter worked examples and expansive end-of-chapter problem sets than the previous edition
* 25% more in-chapter exercises (with answers in Appendix B) than the previous edition
* A new focus on green chemistry that reveals how well its principles mesh with those of organotransition metal catalysis
* Introduction of the 18-electron rule (Chapter 3)
* New computational approaches to molecular orbital calculations (Chapter 2)
* 25% more molecular model illustrations than the previous edition. The text now includes more than 600 illustrations and structures, including 120 brand-new figures; all preexisting figures have been revised for clarity and consistency.
Organometallic Chemistry, Second Edition, is supplemented by an Instructor's Resource CD-ROM, which includes all of the figures from the text in electronic format and the solutions to all of the exercises and problems from the text (in an editable Word file format).
- Sales Rank: #1103607 in Books
- Published on: 2009-10-26
- Original language: English
- Number of items: 1
- Dimensions: 7.70" h x 1.30" w x 9.30" l, 2.95 pounds
- Binding: Hardcover
- 752 pages
Review
"Since it first appeared in 1997, "Organometallic Chemistry" by Spessard and Miessler has earned a reputation as a highly readable, thorough text...The book's approach is to first establish a structure-bonding foundation that is based on molecular orbital theory...This sets the stage for a methodical coverage of the full range of reactions of organo-transition metal complexes and many of the practical applications of this chemistryEL[S]ignificant improvements have been made, including the addition of many more problems at the end of the chapters. The added exercises have a widely varied level of difficulty and focus and therefore allow the instructor much more flexibility in the assigned problems. As a result, this text would be well-suited for a course in which applications to organic synthesis are to be heavily emphasized."--Craig Jensen, Organomettalics
From the Publisher
Addressing the need for an introductory Organometallic Chemistry text, Spessard and Miessler have combined numerous illustrations, problems and well-referenced coverage in an overall accessible approach to this subfield of Inorganic Chemistry.
From the Back Cover
Addressing the need for an introductory Organometallic Chemistry text, Spessard and Miessler have combined numerous illustrations, problems and well-referenced coverage in an overall accessible approach to the topic. The text provides an early, comprehensive introduction to qualitative chemistry to lay a foundation for the upcoming emphasis on structure and bonding, a unique way of categorizing organometallic reactions on the basis of whether actions are mainly at metal or at ligand, a thorough discussion of carbene chemistry allowing readers to focus on all aspects of metal carbenes in one chapter (Chapter 10), and numerous applications of organometallic chemistry showing students that field is relevant and growing.
Most helpful customer reviews
6 of 6 people found the following review helpful.
A great book for presenting trz. mets and orgn. metallics...
By Les Kismartoni
Very well written, though some more practice problems would be useful (not to mention a solutions manual...) THe book presents 18 electorn complexes and the like very well and gives many journals as back up references... Gives a great summary of organometallic reactions (CO insertion, Associative, Dissociative, etc) and a really solid and historically grounded intro to the field of catalysis... Clearly written, for the most part, but one section on the Trans effect is a bit ambigous, in the sense that they never really talk about HOW to use it... Sure they mention the idea, but they never address the leaving group... People always confused on that section... So that is my gripe in this otherwise excellent book...
2 of 2 people found the following review helpful.
A simple guide to organometallic chemistry
By A Customer
This book is a wonderfully simple guide to organometallic chemistry. It is very easy to read making it a quick reference for inquiries. I would highly recommend this book to any beginning organometallic student.
1 of 1 people found the following review helpful.
decent, not the best
By Stuart Kyllo
This book is decently written. the first several chapters provide a background introduction into molecular orbital theory with subsequent chapters introducing various ligands and their behaviors in complexes, then reactions and catalytic cycles. unlike other chemistry books i own this one sources the original journal articles of some principal reactions used as examples- which can be helpful for those interested in looking up the original data. one complaint i have is that the book does not provide many examples of types of reactions, nor does it explain the exceptions to rules and why.
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